GPT is required for booting Windows in UEFI mode, while MBR is needed for older Windows versions in BIOS mode.
You can determine if a disk uses GPT or MBR in Windows using Disk Management utility by checking the Partition style in Properties.
Another way is to use Command Prompt by entering 'disk part' and 'list disk'. An asterisk(*) under GPT column indicates GPT disk.
PowerShell can also be used to check partition style. To convert MBR to GPT on Windows, follow a detailed guide when errors occur during clean installation.