Word2vec is a neural net that processes text, grouping vectors of similar words with two methods: CBOW and skip-gram.Spacy's larger English model includes word vectors, which can be utilized for various tasks like document2vec.Word vectors provide semantic relationships, like similarity between words, based on cosine similarity.You can check if a word is outside vocabulary using attributes such as has_vector and is_oov.Vector arithmetic allows for operations like 'king - man + queen = queen' to explore relationships among words.VADER is a sentiment analysis tool sensitive to polarity in text data, analyzing sentiment without pre-labeled data.VADER uses a dictionary to map lexical features to sentiment scores, considering words' intensity and context.NLTK's VADER tool can be used to analyze sentiment in text data, detecting positive and negative sentiments.Colab file for Amazon reviews sentiment analysis with VADER is available for further exploration.