Molecules known as ligands attach more densely to flatter, platelet-shaped semiconductor nanocrystals than they do to spherical ones.The density of the ligand oleylamine (OLA) is highest on the surface of nanoplatelets, followed by nanorods and nanospheres.Nanocrystal shape plays a role in ligand density due to the ability of ligands to stack more tightly on flat basal planes of nanoplatelets.The findings have implications for improving LEDs, solar cells, and applications in biomedicine through targeted drug delivery.