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Physicsworld

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On the proper use of a Warburg impedance

  • Recent battery papers commonly employ interpretation models for which diffusion impedances are in series with interfacial impedance.
  • A general approach is presented that shows how the charge-transfer resistance and diffusion resistance are functions of the concentration of reacting species at the electrode surface.
  • The resulting impedance model incorporates diffusion impedances as part of the interfacial impedance.
  • Mark Orazem, a Distinguished Professor of Chemical Engineering, discussed these issues during an interactive Q&A session after his presentation.

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