Scientists at Northwestern University have discovered why the process of splitting water to form oxygen during the oxygen evolution reaction (OER) takes more energy than predicted by theory.
Water molecules on the surface of an electrode flip just before they give up electrons, resulting in inefficient water splitting.
The researchers have identified that controlling the orientation of water at the electrode-water interface could improve the efficiency of the OER.
The findings could have implications for multiple energy-related technologies beyond water splitting, such as the hydrogen evolution reaction and CO2 reduction to liquid fuels.