Scientists at the Max Planck Institute for Sustainable Materials have developed a process that combines dealloying and alloying to create nanostructured alloys that are both lightweight and strong, according to research published in Science Advances.
The researchers repurposed dealloying's ability to selectively dissolve metal alloys by harnessing reactive gas. Ammonia is added as a nitrogen donor and the process extracts oxygen and hydrogen to create porosity.
Substitutional alloying then occurs, allowing solid-state interdiffusion between metallic elements after the complete removal of oxygen.
This is followed by interstitial alloying, where nitrogen from the vapor phase infiltrates the host lattice of the newly formed metals. Finally, phase transformation processes are triggered, leading to thermally-induced martensitic transformations, a crucial pathway for achieving nanoscale structuring.
This approach enhances mechanical properties and introduces interstitial nitrogen to fortify the material while reducing carbon emissions and water waste.
The process creates sustainable, lightweight alloys that could be used in the automotive, aerospace, and energy storage industries, among others. The study predicts iron-nitride-based hard magnetic alloys could outperform current rare-earth magnets, leading to more efficient energy solutions.
The rethinking of traditional metallurgical processes opens up a plethora of new avenues in material science, inspiring further innovations in sustainable materials.
This research experience was generously provided by the Alexander von Humboldt Foundation, along with additional support through a European Advanced Research Grant and a Cooperation Grant awarded by the Max Planck and Fraunhofer Societies.
By reframing traditional metallurgical processes, MPI-SusMat’s research opens up opportunities for reducing the reliance on rare earth materials and high-purity feedstocks, aligning with global sustainability aspirations.
This pioneering work is expected to inspire further innovations in sustainable materials, establishing a new paradigm in the field of metallurgical engineering.